Principle of energies summation of an arbitrary system sets the order of
inclusion of various types of energy, associated with the system, into energy
functions that describe the state of the system. Energy summation is most
frequently used in theoretical physics, where principle of least action is used,
total energy of systems is calculated and the law of energy conservation is
taken into account. Principle
of energies summation on the one hand is a methodological principle, but on the
other hand – is result of complexity of systems, consisting of matter in
different states, and of fields available in these systems. The complexity
increases due to motion of matter and fields during transitions of matter from
one phase state to another, and during transformation of energies of fields and
matter into each other.
Energy functions have different meaning depending on their purpose. To estimate
change in energy of a system we need to take into account that some components
increase energy, and others reduce it, which leads to different signs before
energy components. If energy functions are used to find equations of motion,
the signs before the energy components are chosen according to condition of
conforming to the equations of motion of matter and fields. As a result, for each energy function its own order of
energies summation is used.
Contents
o
1.6.1 Einstein-Hilbert
equations o 1.6.2 Equations of CTG
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To calculate the energy functions in thermodynamics such
physical quantities are used as pressure , volume
, absolute temperature
, heat capacity
, mass
, amount of substance
. These quantities can be well measured,
in contrast to entropy
, chemical potential
, amount of heat
, which are characteristic of substance. Internal energy
and its increment
for
multiphase substance in a quasi-static process are given by:
,
,
where is
the increment of the amount of heat,
is the work done by the system,
is the number of substance phases,
is the work done on the system.
Besides the internal energy in thermodynamics there are
other energy functions associated with it, such as Helmholtz free energy:
.
Accordingly, the increment of the Helmholtz free energy
is:
.
Enthalpy and its increment are as follows:
,
.
Gibbs free energy and its increment are:
,
.
Grand thermodynamic potential and its increment are:
,
.
Bound energy and its increment are:
,
.
Two thermodynamic potentials and their increments are
also possible:
,
,
,
.
The order of addition of energy components is of such
kind that we obtain corresponding thermodynamic potential, which has its own
meaning. Thus, internal energy reflects the law of energy conservation, and
change in Helmholtz free energy in an isothermal process is determined only by
difference in work done by the system on environment and by the environment on
the system.
Many relations of thermodynamics hold well not only for gas,
but also for fluids and substance in solid state.
One of the ways to find equations of motion of systems
and laws of their existence is variation of the action functional, that is,
variation by different variables of the time integral of Lagrangian, in order
to determine the extreme and most probable states. Lagrangian
consists of several energy components, which
in mechanics are either part of kinetic energy
or of potential energy
. In order to find the Lagrangian in
mechanics the difference between kinetic and potential energies is written as
follows:
.
It is generally assumed that Lagrangian depends only on
time, coordinates and velocities, but does not depend on the higher time
derivatives.
Since matter in
each mechanical system is a source of its own fields, then in expression for
Lagrangian in general case, terms associated with energies of these fields are
added. In
special relativity, Lagrangian of a particle with mass and charge
in
electromagnetic field has the following form: [1]
,
where is
speed of light,
is spacetime interval,
is electromagnetic 4-potential with lower (covariant) index,
is
4-displacement vector of particle,
is
electric constant,
is
electromagnetic field tensor,
is 4-volume,
is
velocity of the particle,
and
are scalar and vector potentials of electromagnetic field, respectively,
and
are electric field strength and magnetic induction, respectively.
In this case, the Lagrangian includes three components
with dimension of energy, which are associated with relativistic energy of the
particle, with energy of the particle in electromagnetic field, and with
electromagnetic field energy. The expressions for energy components and the
signs before them are chosen so that by varying the action functional we would
obtain equations of particle’s motion in the field and Maxwell's Equations for
field strengths.
Similarly, Lagrangian is written for a single particle in
gravitational field in Lorentz-invariant
theory of gravitation: [2]
where is
gravitational four-potential with lower
(covariant) index,
is the gravitational constant,
is gravitational tensor,
and
are scalar and vector potentials of gravitational field, respectively,
and
are gravitational field strength and gravitational
torsion field, respectively, and mass
not only takes into account sum of nucleons masses of matter, but also
contribution of mass-energy of fields interacting with matter and changing
particle mass.
After varying the action functional we obtain equations
of motion of particle in gravitational field and Maxwell-like gravitational equations for
gravitational field
strength and torsion field.
To use the Lagrangian in any frames of reference, it should be written in
covariant form. In curved spacetime interval can be expressed using metric
tensor :
and instead of component of 4-volume during integration over the 4-volume we
should use the product
, where
is
determinant of metric tensor.
In classical mechanics, Hamiltonian of system of
particles can be defined with the Lagrangian: ,
where is
generalized momentum of i-th particle, and
is
its generalized velocity.
For conservative systems in which the energy is
conserved, the Hamiltonian as a function of generalized coordinates and momenta
is equal to the total energy of
the system and has the following form:
.
In this case, we see that distinction between Lagrangian
and Hamiltonian is in different signs before potential energy of
the system.
Invariant energy of
a body is defined as relativistic energy, measured by an observer who is fixed
relative to the body’s center of momentum. Standard approach involves summation of all
types of energy of the body:
,
where is
rest energy of individual matter particles,
is pressure (compression) energy of matter understood as potential energy
of interatomic interactions,
is thermal energy, which being summed with
yields internal energy,
is
gravitational energy of the body, including energy of proper field in the body
matter and beyond it and gravitational energy in field from external sources,
is
electromagnetic energy of the body,
is
energy of radiation
interacting with the body matter.
In general relativity this leads to the fact that a heated body
should increase its mass, and the mass of a gravitationally bound body should
be less than total mass of particles of matter that forms this body.
There is an alternative point of view that energy
components are included in equation for invariant energy with negative signs: [3] [4] [5]
[6] [7]
.
As a result, heated bodies should have less mass than
cold, and mass of a star must be greater than the mass of scattered matter from
of which it was made up during gravitational collapse.
The third
approach involves rethinking the nature and order of summation energies
in covariant theory of gravitation (CTG). Method of calculating invariant
energy depends essentially on how to account for scalar curvature and
cosmological constant in energy. In
particular, the cosmological constant can be calibrated in such a way as to
exclude the scalar curvature, and thus find a unique expression for the energy. [8] Another innovation is that instead
of standard stress-energy tensor of matter, taking into account inner pressure,
in consideration introduces two new vector fields –acceleration field and pressure field, with corresponding
stress-energy tensors. If we add electromagnetic and gravitational fields, then
obtained four fields symmetrically involved in Lagrangian and energy. Calculation of invariant energy in
spherical body shows that components of energy of all four fields cancel each
other. Therefore contribution to invariant energy of
system makes only potential energies of particles which are under influence of
fields. [9] These energies are also partially
reduced, and for invariant energy can be written:
Relation
for mass is as follows:
where mass and charge
are calculated by integrating corresponding
density by volume of the body with radius
, system mass
equals total mass of particles
,
mass
equals gravitational mass
, and excess
over
is due to the fact that particles move inside
the body and are under pressure in gravitational and electromagnetic fields.
A more accurate expression is presented
in following articles, [10] [11] where for energy and
mass there is the following:
Here gauge mass is related to cosmological constant and represents
mass-energy of matter’s particles in four-potentials of the system’s fields;
is inertial mass; auxiliary mass
is equal to the product of particles’ mass
density by volume of the system; mass
is sum of invariant masses (rest masses) of
the system’s particles, which is equal in value to gravitational mass
.
In contrast to invariant energy, relativistic energy
generally includes additional energy components associated with the motion of
the system as a whole. As a result, in formulas for the energy dependence on
velocity can be determined, such as on the velocity of the center of momentum of the system. If in Minkowski space
invariant energy
is
known, then the relativistic energy in an arbitrary inertial reference frame is
found using the Lorentz transformation by the following formula:
.
For
continuously distributed matter in curved space-time, expression for energy of
a physical system has the following form:[12]
In this expression,
Lagrangian density of the system is presented as sum of two parts
, where
depends on four-potentials and four-currents, and
contains tensor invariants of fields. The quantity
is that part of Lagrangian which is obtained by integrating
over moving volume of the physical system. In matter of the system
velocity of particles is
, the quantity
is time component of four-velocity of these particles,
is determinant of metric tensor. When calculating contribution of
particle fields to energy of the system it is necessary to divide matter
into
particles or elements of matter of point sizes. Each such particle
has some velocity
, while
and energy of the system
in general case depend on the velocities
.
For four
vector fields, the energy is expressed through scalar potentials of
fields , through vector potentials of the fields
, and through tensors of the fields
:
Einstein-Hilbert equations of general
relativity (GR) are aimed to find metric in curved spacetime and are written in
tensor form:
,
where is
Ricci curvature tensor,
is
scalar curvature,
is
cosmological constant, and
is
a stress-energy tensor with dimension of volumetric energy density,
is
Newton's gravitational constant.
In GR and tensor
usually includes stress-energy tensor of matter
and stress-energy tensor of electromagnetic field
:
.
Absence of stress-energy tensor of gravitational field as
a source affecting the metric in GR is due
to the fact that gravitational field is identified with geometrical field in
the form of metric field, and this field does not generate itself (absence of
self-action of the metric field).
Equations of CTG
In covariant theory of
gravitation (CTG)
equations for metric are as follows: [8] [13]
where the
coefficient is found from equations of motion
of particles and waves in any given form of metric, and the tensor
is sum of four tensors:
where
is stress-energy tensor
of gravitational field,
is acceleration stress-energy tensor, and
is pressure stress-energy tensor.
This
means that in CTG gravitational field is a physical field and along with
electromagnetic field, acceleration field and pressure field it is the source
forming spacetime metric.
For the
case of continuously distributed matter we obtain
equality for cosmological constant:
where and
are the mass and electromagnetic
4-currents, respectively,
and
– 4-potentials of acceleration
field and pressure field.
The
covariant derivative of the left side of equation for metric due to calibration
of cosmological constant and scalar curvature is zero. This allows us to write
equation of matter motion as equality to zero of covariant derivative of sum of
the tensors in the right side, taken with contravariant indices:
.
In concept of general
field it is assumed that all vector
fields associated with matter are components of this field. 4-potential of
general field is
sum of 4-potentials of particular fields. [14] [15] As a result, the sum of
terms in Lagrangian responsible for energy of matter in various fields, up to a
sign is simply the product of
.
As for the
energy of particular fields themselves, these energies are included in
Lagrangian through the general field tensor
, obtained as 4-curl of the
4-potential of general field. For Lagrangian we
obtain the relation:
where and
are
the constants to be determined;
is
invariant 3-volume expressed in terms of product
of
space coordinates’ differentials and square root
of
determinant
of
metric tensor, taken with a negative sign.
The relativistic energy of the system
is:
where and
denote
the time components of the 4-vectors
and
.
The feature of expression for energy is that in it general field energy in the tensor product includes
not only energies of particular fields, but also cross-terms in the form of a
sum of products of particular fields strengths in various combinations. We can
say that the energy of particles in particular fields is included in energy of
the system linearly, and the energy fields themselves – approximately
quadratically.